I looked it up in the DM referance, and I could't figure it out. I want to pick a mob in the world then have that mob do a certain proc. I want this to be random...
EDIT: I read it again...I saw the bottom that if the only argument is a list, then it will pick someone from that? Soo.... pick(listname) ? That would work, but how can I determine a var to set for one person picked from that list?

Yes. Make sure you always read the reference entries fully - preferably a couple of times at that (if you're having issues).
Welllll... store the value pick() returns to a variable... if you can't figure that out, you should read the DM Guide.